In this video, I make dimethyl oxalate from oxalic acid and methanol. Patreon Link: / dougslab Twitter: @YTDougsLab Google+: plus.google.com/u/1/103236004...
Пікірлер: 333
@ScienceWithJames3 жыл бұрын
Here's an update from Doug that he posted on the Science Madness forum: He moved into a new house and is currently busy with that. He is working on settling in, finding time to do chemistry, and setting up a new lab. He probably won't be back soon, but when he is, expect a new lab setup!
@karolus283 жыл бұрын
cool
@All_Science3 жыл бұрын
@@karolus28 very cool
@karolus283 жыл бұрын
@@All_Science quite indeed
@gabrielbr14592 жыл бұрын
Thanks for clarifying
@dudetapedtoafridge30732 жыл бұрын
OMG YES JAMES HOLY F##K YES
@duyataksis52106 жыл бұрын
Aaaaaaaaaaaand he's gone. Bye, Doug! See you again next year!
@jasonvoorhes34295 жыл бұрын
I need him!!!!
@mikebarnacle14695 жыл бұрын
Happy spiders though
@thetilenglishtaste99134 жыл бұрын
*in 2 years
@n-n.n32484 жыл бұрын
@D. R. yeah YT rules are awful If this keep going like this , every cool chem channel will be banned and only will stand the shitty ones(make slime/playDoh as the "coolest" science projects) :c
@pd1jdw6303 жыл бұрын
It’s now 2 years later.
@BlackWolf42-6 жыл бұрын
I know the family and other commitments take precedence over playing in the lab and doing KZfaq videos. I wish you the best. You are/were the best educational producer in the field of KZfaq chemistry; you can run with the best of them.
@DarkMeta_Minecraft4 ай бұрын
Does he even realize how big his channel has become now?! This is a money maker just sitting here. Man
@b-rad3937Ай бұрын
I don't think he does or he doesn't care
@liamcg25213 жыл бұрын
really miss this channel posting, one of the best.
@RedwoodRhiadra6 жыл бұрын
Doug, I really hope you're all right.
@jhyland873 жыл бұрын
Same..
@NurdRage6 жыл бұрын
If you're going to make trichlorophenol please be careful and thoroughly research the formation of side products like TCDD. I wanted to make TCP awhile back but i decided against it due to TCDD formation.
@mozarellaman12016 жыл бұрын
hadn't even heard of the compound, looks like scary stuff
@AlChemicalLife6 жыл бұрын
Agent Orange :( , be careful Doug !
@NatasPvPMontagesz6 жыл бұрын
He didnt post anything in a month, did he died?
@bigboineptune95675 жыл бұрын
This is scary given the fact that he hasn't posted in 7 months.
@jeffreyfugh76025 жыл бұрын
If a chemical's evilness is enough to deter a hardened badass chemist like NurdRage, it IS really not a good idea to take such a risk.
@unclecrusty19919 ай бұрын
I hope you come back soon Doug. Your videos give me confidence to perform projects myself because of the education you give while talking about some of these chemicals. It'd be like Christmas to see you uploading again. Hope to see you soon.
@CollegeChemistry6 жыл бұрын
Doug the videos just keep rolling out from you, and I'm loving it.
@Spycyzygy4 жыл бұрын
This comment aged poorly rip
@OkieDokieSmokie4 жыл бұрын
@@Spycyzygy very poorly...
@miabobeea26444 жыл бұрын
F
@cockatieltime22593 жыл бұрын
Rip doug :(
@GrimStarr2 жыл бұрын
@@Spycyzygy hahaha
@hopeforescape8842 ай бұрын
I just wanted to thank you for being an inspiration to me, I am three weeks away from graduating with a bachelor's in chemistry, and I will be starting grad school this August, I started watching you all the way back in middle school, it sad you have not continued to upload, but none the less thanks for your videos!
@brandonross60834 ай бұрын
It's sad he disappeared like that though. He had a talent with this. Probably the best chem tuber out of them all and he wasn't even around long enough to reap any benefit from it. His videos have more potential than any chemistry videos I've ever seen on KZfaq
@subliminalvibes6 жыл бұрын
Haha.. you're a cool dude, AND a great orator of chemistry. Thank you, Doug. I'm really looking forward to what you've got planned.
@DavidJohnson-ty8qz Жыл бұрын
Doug. Please come back!!!!! We miss seeing your content.
@grantstech.6 жыл бұрын
I’ve been waiting so patiently all day. So relieved that you actually uploaded. As always love the video!
@caltto13612 жыл бұрын
Doug come backkkkkk we need our Chemistry king backkkkk
@lastplace1996 жыл бұрын
Is doug dead or taking another year long hiatus? Find out next year on Dragon Ball Z.
@AtlasReburdened4 жыл бұрын
And then the f*%&ing series just restarts.
@shinyblu21444 жыл бұрын
as i saw this comment i was playing dbz2
@MobscastBlackOut3 жыл бұрын
He's dead rip
@Adventist99173 жыл бұрын
@@MobscastBlackOut Is he actually???
@jhyland873 жыл бұрын
@@Adventist9917 i think hes just joking.
@ph08nyx Жыл бұрын
Now we will never know what this super secret and super cool reaction is! I feel miserable!
@normellowАй бұрын
Let’s go Doug ! Chemistry doesn’t wait for nobody !
@zock44196 жыл бұрын
I think your videos are great and it's pretty awesome to be able to expect the release date of the new videos!
@senorjp219 ай бұрын
Hey Doug. Thanks for all these videos. They are excellent. I wish you would make more, but you do you. Cheers
@atomicreactions92012 жыл бұрын
Since you quit upoading videos I feel like a forgotten lab spatula in an acid solution.
@ScienceWithJames6 жыл бұрын
Great video, as always, Doug.
@mrjcaudy6 жыл бұрын
Doug where are you?
@vojtechpesl44715 жыл бұрын
Doug, please come back !
@michaeldomansky84975 жыл бұрын
Where were all these great "teachers" when I was in school! Doug, come back!
@moritzschaferalthaus34616 жыл бұрын
Hi Doug In your last Lab Tour for 2500 subscribers you said you will make a more detailed Lab Tour in the future.Can we see that in one of your next videos? I love your channel and im so happy that you‘re back.
@Josezwitterion3 жыл бұрын
I miss you DOUG
@repomandan076 жыл бұрын
Love that opening for your patreon supporters.
@svoranger3 жыл бұрын
@Doug's lab, When work slows down and family life allows, hope to see some new videos from you. And I think your channel is every bit as good as Nile Red and Nerd Rage.
@praspurgh Жыл бұрын
I remember watching your videos like about 10 years ago, and this video pops up on my home page. still same voice and lab lol
@buttmeister6 жыл бұрын
I did enjoy it and your videos are very educational so i became a patreon thanks
@hongbitter71425 жыл бұрын
More videos Doug! We need more
@MrCrazyChemist6 жыл бұрын
Loving the new content, I think that if you put a piece of hose on the bottom of your aspirator it would be a lot quieter. Mine sure is
@hubrisnaut3 жыл бұрын
Hey Doug, Your videos are awesome. Any chance you will make more? Hope you are well.
@drkaranmannan6 жыл бұрын
Please don't stop uploading. Your Channel is bound to grow. Collab with codys lab maybe?
@jozefnovak7750 Жыл бұрын
Super! Thank you very much!
@spinjector6 жыл бұрын
Hi Doug. I'm a fan of your videos and watch them regularly. I have some suggestions to improve the sound quality of your audio. I'm not sure what you record with, if it's a video camera or cell phone. If it's a cell phone, the solution is easier, see if you can use a bluetooth headset with noise cancellation. First, it will get the microphone closer to your mouth so the sound of your voice is louder in comparison with the noise in the background. If you're using a video camera with a microphone input, get one of those over the ear microphones like you see rock stars using and plug it into the microphone input. Either solution should be able to be had for an economical price. Ebay and Amazon are overflowing with bluetooth microphones, and the over-ear performance microphones can be had at any music store. Whichever one it is, be sure to look for the terms noise-cancelling, directional, or if it's a performance microphone, look for the term cardioid pattern. Barring technological improvements, there are three main sources of noise in your videos: the aspirator, the vent fan, and OMG THAT SQUEAKY LAB JACK lol. Please, for the love of everything and anything to do with my eardrums, please put some grease on that lab jack lol. If you're concerned about volatile hydrocarbons that may interact with any of your experiments, I understand, but perhaps you could just use a dab of that heavily fluorinated grease that you use to grease your glass joints. Should be no reaction problems there, eh? The vent fan would require a little more engineering, and might be more difficult to replace. But with fans, slower and bigger is quieter. Perhaps one of those big white plastic house fans that people get for the summertime? Also with a larger fan, the frequency of the noise it generates would be lower, and less likely to pierce through to the microphone and the recording. And lastly, the remaining screaming roar in your videos is the aspirator. The solution to there is simple, just get a piece of hose about 12 to 18 in long and jam it on the outlet. Make it just long enough so that you can lay the end down in the sink, or put it right down in the drain. Or possibly just in a container sitting on the bottom of the sink to catch the water, after which it can gently overflow and then go down the drain. Peace out bro, keep up the good work.
@LockeSoriku3 жыл бұрын
Great video. Seems as though I arrived after the end. Hopefully, he returns.
@arjunyg46554 жыл бұрын
we miss you Doug!
@verdatum3 жыл бұрын
I miss you, and your videos.
@cvabds6 жыл бұрын
I love your vídeos, i need them, NileRed does pretty good explanation and video editing, hope you get your patreons UP, you should do some promotion of your channel somewhere.
@Correct_Opinion2 жыл бұрын
We miss you :(
@johnblacksuperchemist25562 жыл бұрын
GREAT VIDEO
@matthewcncsutton52832 жыл бұрын
Hope to see more videos some time doug
@mistertheguy30736 жыл бұрын
Hey, I love chemistry too!
@Psychx_6 жыл бұрын
Doug please come back!
@erictorkelson57786 жыл бұрын
Definitely too much H2SO4. I copied your prep this week also running it on the 1 m scale but reducing the sulfuric acid to 25ml. No issues drying it on the pump and it proceeded at essentially the same speed. Followed up with a re-xtal in hot MeOH to clean off lingering sulfuric.
@bearcatben47624 жыл бұрын
I can't believe its been more than a year now
@Christopher.Marshall5 жыл бұрын
Doug, in another video not too long before this one you said you were going to produce videos more frequently but you haven't followed through. When can we expect to see more of your chemistry?
@samwheller5 ай бұрын
Hope all is good. Feel like, given the era, fate might have given us Doug's Lab > Cody's Lab had things continued.
@feIps_4 жыл бұрын
Not again Doug. I have a heart, you know?
@RushilFernandes6 жыл бұрын
Thanks for posting. It's always fun to watch organic synthesis videos. I would like to ask, however, why you don't use TLC to monitor the progress of your reactions. It would make things so much easier IMHO. I spent my PhD constantly doing column chromatography and TLC and for some reason I haven't seen a single KZfaq chemistry person do either.
@RobsMiscellania4 жыл бұрын
I was similarly dissatisfied with the lack of chromatography on KZfaq as well, so I decided to equip myself and I will shortly be producing videos for my channel. I will be presenting organic synthesis with applications to medicinal chemistry and will be prominently featuring the use of TLC and column/flash chromatography. Since I plan on making series of videos of multistep syntheses, it will sometimes be required for me to purify a compound I have synthesized in order for the next step of the synthesis to take place successfully. I will also be using melting point, refractive index, and colorimetry where applicable in order to more fully characterize these sets of compounds. I hope you'll join me for some exciting chemistry! I plan to begin with an example of the Sandmeyer reaction shortly after the beginning of the new year.
@user-ns7ng6xm3p4 ай бұрын
پس چیشد محتوای ویدئو شیمی که گفتی @@RobsMiscellania
@drkaranmannan6 жыл бұрын
10:21, Doug, you're an artist. ( you'll probably catch the reference...)
@snowdaysrule6 жыл бұрын
Ay we have the same fritted vacuum filtration funnel! 150ml #3 medium porosity haha
@XC2long4u6 жыл бұрын
Could you do a video on hardware? Cheap glass vs expensive glass, different brand mantles etc.
@sundayjohn56195 жыл бұрын
Pls, doug, i want to know how to prepare molybdenum oxalate and nickel oxalate. Thanks
@jordanandrews64795 жыл бұрын
Come back, Doug! This shit is mint
@mihneasimionescu20223 жыл бұрын
It has been two years... what happened to Doug? He was my favorite teacher...
@tmd94123 жыл бұрын
He got married and moved to somewhere without internet
@eshwarseplay6 жыл бұрын
Could this work as a replacement for Oxalyl Chloride in synthesis of bis(2,4,6-trichlorophenol) oxalate
@cognitivedissonancer6 жыл бұрын
Doug's mysterious disappearances cannot but remind me of Twin Peaks.
@theginginator14886 жыл бұрын
Really cool video! I thought the liquid would be way more viscous than it was
@mrchangcooler5 жыл бұрын
He's going, he's going, and he's gone ladies and gentlemen. It was a good little run while it lasted.
@gayrainbowunicorn13676 жыл бұрын
Are you going to prepare some glowsticks with TCPO?
@mwilson146 жыл бұрын
I'll be watching this one later. I experimented quite a bit with oxalate compounds for a couple months and have been hoarding Oxalic acid since Bartell's was selling it buy one get one free.
@DougsLab6 жыл бұрын
I want to see what you come up with!
@mwilson146 жыл бұрын
Good deal and I'll be making videos again soon which will be better quality than my previous number of low quality posts. I have a fair amount of ferrous oxalate and even more potassium ferrioxalate, the latter of which I need to use soon since K3Fe(C2O4)3 is very light sensitive and will decompose and become useless. I was thinking about making calcium oxalate to simulate kidney stones. LOL. I have a microscope with a mounted camera that I'd like to upgrade so I can take non-choppy video and make that into a theme for my channel. I don't see tons of people doing micrograph photo/video stuff and I'd like to see others doing a lot more of that. I usually use my camera on my phone out of convenience of not having to hook the microscope up to my laptop, plus I can get a better picture since my phone has a higher resolution. I updated my google header photo with phosphate stabilizers I isolated from a Pepto Bismal bismuth extraction and lit it with UV light under my microscope. It's a pretty cool photo if you want to check it out.
@mwilson146 жыл бұрын
I just found out something that made me jump up with excitement as I've been working on crystallizing neodymium sulfate for a couple of months! I have a small bit of crystals but haven't grown since they formed weeks ago. They are a beautiful lavender color. Most everything else I have created so far is clear, white, yellow, green, blue and dirty orange in color. I do have my nearly black copper acetate crystals, which I've been very fond of, but nothing yet beats the neodymium sulfate crystals. There is a topic I found on the Sciencemadness forums and it involves extracting the Nd from solution by precipitating it out via an oxalate. I've not found too much info on Nd, but I guess I wasn't searching incredibly hard either. I didn't realize that Nd is less soluble in near boiling water than it is in cold!
@mwilson146 жыл бұрын
I posted a short video on my channel of the results from my neodymium extraction experiment using oxalic acid. I'll be making a how-to video on the subject in the future. kzfaq.info/get/bejne/rrWTYKuj3djGlmw.html
@Spycyzygy5 жыл бұрын
Rip Doug again
@doppler32376 жыл бұрын
where did he go?
@zelaboratorium87536 жыл бұрын
where are the promissed videos doug ? we miss you :,(
@SD-fw9li6 жыл бұрын
Oh heck yeah
@spookywizard49806 жыл бұрын
How come you used so little methanol? Isn't the standard procedure to use a large excess maybe x2 or x3 to strongly favor products?
@user-gp9kk8co9w6 жыл бұрын
where are you?
@thenewbgamer64164 жыл бұрын
Im glad to see a 或那个 caring for Doug.
@FantomZap5 жыл бұрын
I'm sad, where'd Doug go again?
@drewlew185 жыл бұрын
Please come back Doug :)
@miabobeea26444 жыл бұрын
"as I'll be showing in some upcoming videos" gdi Doug
@miabobeea26444 жыл бұрын
I hope he's okay...
@andrewandrei30623 жыл бұрын
@@miabobeea2644 I hope that too
@keymaster21085 жыл бұрын
Make a video on Distillation of kerosene. I know it seems basic but very little info is available about this on the web
@tmfan38886 жыл бұрын
how do u know the rxn has almost completed after merely 10min on the hotplate?
@drysori6 жыл бұрын
Why do you leave the stir bar?
@muhammadizazhashmi75316 жыл бұрын
Love your videos. Please do a detailed video on all the glassware you have. Thanks for the awesome content.
@LegendaryShorts3710 ай бұрын
Mau nyabu lu ya
@GLITCH_-.-6 жыл бұрын
I like the speed you're talking at! :D Sometimes I have to speed up a video because the dude is unbearable slow. Your speed is perfect. :) One question: Can you put a hose on the faucet or would that kill the vac? I never used an aspirator, but I think that could work. On the other hand, you probably would have thought of this before me. (Sentence seems clumsy... I'm german) :P
@DC_DC_DC_DC6 жыл бұрын
Distelzombie Centzon Totochtin maybe just a slope or slide so it doesn't hit the sink
@GLITCH_-.-6 жыл бұрын
yea, that would work. :)
@science_and_anonymous6 жыл бұрын
LETS SEE A VIDEO DEVOTED TO SOLVENTS!!!
@jamesg13676 жыл бұрын
Nice. If there's residual H2SO4, is it an issue wrt your intended experiments?
@DougsLab6 жыл бұрын
Not if I use an excess of the required catalyst, which is strongly basic! *hint*
@jamesg13676 жыл бұрын
I can hazard a guess. Maybe this: onlinelibrary.wiley.com/wol1/doi/10.1002/cctc.201300209/full Or maybe this: page-one.live.cf.public.springer.com/pdf/preview/10.1007/BF00910842
@EthnobotanikFAQ6 жыл бұрын
I guess the product will glow :D ohh he already revealed it..
@mowskii57916 жыл бұрын
Doug's Lab Hmmm... I know Chemplayer did a video like that
@user21XXL6 жыл бұрын
N(Et)3 ?
@diegocrescente87856 жыл бұрын
Would a Dean-Stark have helped to increase yield?
@andreapozzi34666 жыл бұрын
Can you make a video about wurtz-fittig reaction?
@pietrotettamanti72394 жыл бұрын
Please come back doug
@darianballard20746 жыл бұрын
Hello Can you please help me out by making a video on this. Have you ever seen any information on production of Tetraethyllead ? I can't find a good Grignard Reaction with all the info i need. With the dos and don't and whats needed.
@KallePihlajasaari3 жыл бұрын
For those wanting to play with such compounds be aware that they are neat the top of the list of toxic chemicals. Make sure you have safe ways of cleaning your glass and disposing of the residues.
@AntiProtonBoy6 жыл бұрын
We love chemistry, too, internet friend.
@hopeforescape8843 жыл бұрын
I miss you its been 3 years... 😢
@gmglabs53956 жыл бұрын
I think I know what you have got planned for the dimethyl oxalate... I remember reading a bunch of old DuPont patents relating to it lol.
@dhawthorne16346 жыл бұрын
Taking this way further than Nurdrage did. I always wished he'd shown how to do this from scratch.
@AtlasReburdened4 жыл бұрын
We miss you, Doug. I hope Chicago didn't get you.
@Guido1255 жыл бұрын
Hope you're doing ok! I miss your videos.
@midwestchem36811 ай бұрын
Doug we all hope you're doing great! Does anyone know if alkylation of phenol can be accomplished using dimethyloxalate?
@ar-l6 ай бұрын
Yes, it's possible with phenol, K2CO3 and DMF as a solvent
@codycarlson69635 жыл бұрын
What watch are you wearing
@ggggosebssp5 жыл бұрын
What with all that upcoming videos, I watched all of tour videos already and I want more
@nexa80575 жыл бұрын
Can u make Cyclohexylamine ??
@leonardomarinovic34926 жыл бұрын
Are you ok?
@pyromen3216 жыл бұрын
Hey Doug, mind if I ask what you do for a living? I'm unsure if you work in a chemistry-related field or if chemistry is simply one of your hobbies
@seanm36446 жыл бұрын
I'm also curious about this
@DougsLab6 жыл бұрын
I work in the automobile airbag industry, which has a lot to do with mechanical engineering but also the chemistry of explosives and propellants, which is my major field of study.
@oliverrapp936 жыл бұрын
Doug's Lab heyyyy make some azides
@thenewbgamer64164 жыл бұрын
He answered this. He is alive... [Things intensify]
@brandonhemphill68162 жыл бұрын
@@thenewbgamer6416 yeah 4 years ago
@user-ls3ny1qk4z3 жыл бұрын
Is it so dangerous chemical?
@geeder90862 жыл бұрын
What is "transistorification"? Is that how transistors are made -- LOL. Thanks for another excellent video!
@emmepombar33283 жыл бұрын
Hey Doug, are you alright? We are missing your awesome videos.
@tmd94123 жыл бұрын
He got married and moved to somewhere without internet
@ElizabethGreene6 жыл бұрын
Someone should make a beaker that is slightly tapered outward so it's easier to remove products like the big cake at 7:35