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Sn1 and Sn2: summary

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Khan Academy Organic Chemistry

Khan Academy Organic Chemistry

Күн бұрын

Пікірлер: 18
@user-tf5lz9wo2n
@user-tf5lz9wo2n 6 жыл бұрын
in minute 6.00 you didn't rearrange the carbcation from secondary to tertiary. is this just to complete the example about the secondary substrate or this is the right mechanism of this reaction? because if you rearranged the carbcation the product would be different.
@herbertgunther8951
@herbertgunther8951 3 жыл бұрын
how would you rearrange the substrate to tertiary?
@kyle9008
@kyle9008 3 жыл бұрын
@@herbertgunther8951 hydride shift
@herbertgunther8951
@herbertgunther8951 3 жыл бұрын
@@kyle9008 is not possible with this substrate, or do i overlook sonething?
@peybak
@peybak 3 жыл бұрын
@@herbertgunther8951 It's a benzene ring. You're right. Can't put a positive charge there.
@kialuvsyoo
@kialuvsyoo 3 жыл бұрын
How are we supposed to know when the nucleophile splits up and when it doesn't? Also, for the 3rd reaction, how did you know to use the double bonded O for bonding as opposed to the one part of the alcohol group (I've always seen the alcohol group referred to as the nuceophile)??
@peybak
@peybak 3 жыл бұрын
He had to do it because he is showing an SN1 reaction. If he deprotonates the oxygen like you're saying, then he'll have a strong nucleophile which will then go thru an SN2. I think he picked a complicated example that's a little confusing.
@herbertgunther8951
@herbertgunther8951 3 жыл бұрын
can`t water deprotonate formic acid and the O- is then the nucleophile?
@peybak
@peybak 3 жыл бұрын
I have a feeling that the mechanism for that reaction isn't the best. If you think about it, he has to use the carboxylic acid as is, so that the nucleophile is not too strong (because he is showing SN1). That's why he didn't deprotonate the hydroxyl group there. It's not the best example he could come up with.
@eneryi4457
@eneryi4457 5 жыл бұрын
in the first example, isn't iodide a bad leaving group because in a protic solvent like ethanol, iodide is a strong nucleophile?
@danielberger9772
@danielberger9772 2 жыл бұрын
No. Iodide is a good leaving group because it's a very weak Bronsted base. Not all strong nucleophiles are also strong bases, even though almost all strong bases are good nucleophiles.
@RomanReigns-me2pg
@RomanReigns-me2pg 5 жыл бұрын
Sir how can i get hindi or Gujarati languages videos
@Nathan-or2hl
@Nathan-or2hl 4 жыл бұрын
What happens if you have weak nucleophile but polar aprotic solvent?
@kyle9008
@kyle9008 3 жыл бұрын
sn1
@zakmes8901
@zakmes8901 7 жыл бұрын
Hi khan. Can tell me the name of program you are doing courses and lessons on youtube? I want it for writing drafts and structure of molecules. Thankd bro
@marcelorabello7
@marcelorabello7 3 жыл бұрын
Zak, did you get the answer? I also want to know the name of the program.
@snehansumohapatra8930
@snehansumohapatra8930 6 жыл бұрын
U briefly understand the meaning organic substrate how they react with solvent attacking the nucleophile to form the stable products however the product formed need some help of writing the trickiest stru.
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